Фотовольтаические свойства функционализированного индодикарбоцианинового красителя

Авторы

  • Н.Х. Ибраев
  • Е.В. Селиверстова
  • Г.С. Омарова
  • А.А. Ищенко
  • Н.А. Деревянко
  • Т. Хамза

DOI:

https://doi.org/10.31489/2022No3/55-59

Ключевые слова:

полиметиновые красители, функциональные группы, оптические свойства, фотовольтаика

Аннотация

Изучено влияние химического строения полиметиновых красителей на их спектрально-люминесцентные и фотовольтаические свойства. Показано, что введение функциональных групп в структуру красителя приводит к батохромному сдвигу полос поглощения и флуоресценции. При адсорбции красителей на поверхности диоксида титана был зарегистрирован сдвиг их спектров в область красных длин волн с одновременным уширением полос, вызванных агрегацией красителя на поверхности полупроводника. Зарегистрировано уменьшение времени жизни возбужденного состояния молекул на 64 и 30% для красителей 1 и 2, соответственно. Тушение времен жизни флуоресценции адсорбированных молекул является результатом передачи электрона от красителя к полупроводнику. Измерения фотовольтаических параметров солнечных ячеек, сенсибилизованных исследуемыми красителями показали большую эффективность для функционализированного красителя, что связано с более лучшей адсорбцией данного соединения на TiO2.

Биографии авторов

Н.Х. Ибраев

Doctor of phys.-math. sciences, Professor, Director of the Institute of Molecular Nanophotonics, E.A. Buketov Karaganda University, Kazakhstan. Scopus Author ID: 9333698600, ORCID ID: 0000-0002-5156-5015

Г.С. Омарова

PhD, E.A. Buketov Karaganda University, Kazakhstan; Scopus Author ID: 56669661100, ORCID ID: 0000-0003-2900-2168

А.А. Ищенко

Doctor of chem. sciences, Professor, Corresponding member of the National Academy of Sciences of Ukraine, Head of the Department of Color and Structure of Organic Compounds, Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine. Scopus Author ID: 8338223800, ORCID ID: 0000-0003-2722-3944

Н.А. Деревянко

Senior Researcher, Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine. Scopus Author ID: 35428560600, ORCID ID: 0000-0001-6474-9254

Т. Хамза

Learner, Nazarbayev Intellectual School of Karaganda, Kazakhstan.

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Загрузки

Как цитировать

Ибраев N., Селиверстова E., Омарова G., Ищенко A., Деревянко N., & Хамза T. (2022). Фотовольтаические свойства функционализированного индодикарбоцианинового красителя. Eurasian Physical Technical Journal, 19(3(41), 55–59. https://doi.org/10.31489/2022No3/55-59

Выпуск

Раздел

Энергетика

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